Publications

2009”N@

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Oishi, M.; Kondo, H.; Amii, H.
Aromatic Trifluoromethylation Catalytic in Copper.
Chem. Commun. 2009 (14), 1909-1911.

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Amii, H.; Uneyama, K.
C-F Bond Activation in Organic Synthesis.
Chem. Rev. 2009, 109 (5), 2119-2183.

2008”N@

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Iijima, A.; Amii, H.
Selective Aromatic Carbon-Oxygen Bond Cleavage of Trifluoromethoxyarenes: A Trifluoromethoxy Group as a Convertible Directing Group.
Tetrahedron Lett. 2008, 49 (41), 6013-6015.

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Uneyama, K.; Katagiri, T.; Amii, H.
alpha-Trifluoromethylated Carbanion Synthons.
Acc. Chem. Res. 2008, 41 (7), 817-829.

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Fujioka, Y.; Amii, H.
Boron-Substituted Difluorocyclopropanes: New Building Blocks of gem-Difluorocyclopropanes.
Org. Lett. 2008, 10 (5), 769-772.

2007”N@

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Morishita, M.; Amii, H.
A Study on Ligand-Coupling Reactions of Imidoyl Palladium Complexes.
J. Organomet. Chem. 2007, 692 (1-3), 620-624.

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Guo, Y.; Fujiwara, K.; Amii, H.; Uneyama, K.
Selective Defluorination Approach to N-Cbz-3,3-difluoro-2-difluoromethylenepyrrole and Its Application to 3,3-Difluoroproline Dipeptide Synthesis.
J. Org. Chem. 2007, 72 (22), 8523-8526.

2006”N@

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Akamatsu, C.; Yamauchi, A.; Kobayashi, T.; Ozeki, Y.; Takagi, J.; Amii, H.; Uneyama, K.
An Improved Synthesis of Fluorinated Imidoylsilanes
Synthesis, 2006 (11), 1836-1840.

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Amii, H.; Kohda, M.; Katagiri, T.; Uneyama, K.
Synthesis of 3,3,4,4-Tetrafluoro-1,2-bis(imino)cyclobutanes: A Cyclic Version of Fluorinated alpha-Diimines.
J. Fluorine Chem. 2006, 127 (4-5), 505-509.

2005”N@

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Amii, H.; Uneyama, K.
Mg-Promoted Selective C-F Bond Cleavage: A General and Efficient Access to Difluoroenol Silyl Ethers and Their Derivatives.
Fluorine-Containing Synthons, ACS Symposium Series Book 911, Chap. 27 (V. A.Soloshonok, Ed.), pp. 455-475.

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Amii, H.
The Catalytic Version of Stoichiometric Organic Synthesis.
Lett. Org. Chem., 2005, 2 (1), 5-14 (Highlight Mini-Review).

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Uneyama, K.; Amii, H.; Katagiri, T.; Kobayashi, T.; Hosokawa, T.
A rich chemistry of fluorinated imidoyl halides.
J. Fluorine Chem. 2005, 126 (2), 165-171.

2004”N@

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Uneyama, K.; Tanaka, H.; Kobayashi, S.; Shioyama, M.; Amii, H.
Oxidative Cross-Coupling of beta,beta-Difluoroenol Silyl Ethers with Nucleophiles; A Dipole Inversion Method to Difluoroketones.
Org. Lett. 2004, 6 (16), 2733-2736.

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Suzuki, A.; Mae, M.; Amii, H.; Uneyama, K.
A Catalytic Route to the Synthesis of Optically Active beta,beta-Difluoroglutamic Acid and beta,beta-Difluoroproline Derivatives.
J. Org. Chem. 2004, 69 (15), 5132-5134.

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Amii, H.; Vranicar, L.; Gornitzka, H.; Bourissou, D.; Bertrand, G.
Radical-Type Reactivity of the 1,3-Dibora-2,4-Diphosphoniocyclobutane-1,3-diyl.
J. Am. Chem. Soc. 2004, 126 (5), 1344-1345.

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Scheschkewitz, D.; Amii, H.; Gornitzka, H.; Schoeller, W. W.; Bourissou, D.; Bertrand, G.
sigma-Bond Stretching: A Static Approach for a Dynamic Process.
Angew. Chem. Int. Ed. 2004, 43 (5), 585-587.

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Organometallic News (No.3), 102-102, ‹ß‹E‰»Šw‹¦‰ï—L‹@‹à‘®•”‰ï (2004).

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2003”N@

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Amii, H.; Ichihara, Y.; Nakagawa, T.; Kobayashi, T.; Uneyama, K.
Unusual Reactions of N-Allylic Difluoroenamines under Thermal Conditions.
Chem. Commun. 2003 (23), 2902-2903.

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Kobayashi, T.; Nakagawa, T.; Amii, H.; Uneyama, K.
Mg-promoted Double Silylation of Trifluoroacetimidoyl Chlorides. A New Entry to the Fluorinated Dianion Equivalents.
Org. Lett. 2003, 5 (23), 4297-4300.

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Amii, H.; Kohda, M.; Seo, M.; Uneyama, K.
A Novel Route to the Fluorinated Diimines: Carbon Monoxide-Promoted Reductive Homocoupling of Fluorinated Imidoyl Iodides in the Presence of a Palladium Catalyst.
Chem. Commun. 2003 (14), 1752-1753.

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Kobayashi, S.; Tanaka, H.; Amii, H.; Uneyama, K.
A New Finding in Selective Baeyer-Villiger Oxidation of alpha-Fluorinated Ketones; A New and Practical Route for the Synthesis of alpha-Fluorinated Esters.
Tetrahedron 2003, 59 (9), 1547-1552.

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2002”N@

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Hata, H.; Kobayashi, T.; Amii, H.; Uneyama, K.; Welch, J. T.
A New Sequential Defluorination Route to alpha-Fluoro-alpha,beta-unsaturated Ketones from Trifluoromethyl Ketones.
Tetrahedron Lett. 2002, 43 (35), 6099-6102.

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Scheschkewitz, D.; Amii, H.; Gornitzka, H.; Schoeller, W. W.; Bourissou, D.; Bertrand, G.
Singlet Diradicals: from Transition States to Crystalline Compounds.
Science (Washington, DC) 2002, 295 (5561), 1880-1881.

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Mae, M.; Matsuura, M.; Amii, H.; Uneyama, K.
A Facile Synthesis of Difluoromethylaziridines.
Tetrahedron Lett. 2002, 43 (11), 2069-2072.

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Uneyama, K.; Katagiri, T.; Amii, H.
New Approaches to Stereoselective Synthesis of Fluorinated Amino Acids.
J. Synth. Org. Chem. Jpn. 2002, 60(11), 1069-1075.i—L‹@‡¬‰»Šw‹¦‰ïމp•¶†j

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Uneyama, K.; Amii, H.
Synthetic Strategy to Fluorinated Amino Acids.
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Uneyama, K.; Amii, H.
A review of Mg metal-promoted C-F bond activation; A reliable synthetic approach to difluorinated organic compounds.
J. Fluorine Chem. 2002, 114 (2), 127-131.

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Organometallic News (No.1), 22-23, ‹ß‹E‰»Šw‹¦‰ï—L‹@‹à‘®•”‰ï (2002).

2001”N@

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Amii, H.; Kobayashi, T.; Terasawa, H.; Uneyama, K.
Difluorinated Danishefsky's Diene: A Versatile C
4-Building Block for the Fluorinated 6-Membered Rings.
Org. Lett. 2001, 3 (20), 3103-3105.

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Amii, H.; Hatamoto, Y.; Seo, M.; Uneyama, K.
A New C-F Bond Cleavage Route for the Synthesis of Octafluoro[2.2]paracyclophane (AF4)
J. Org. Chem. 2001, 66 (21), 7216-7218.

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Amii, H.; Kishikawa, Y.; Uneyama, K.
Rh(I)-Catalyzed Cyclization Coupling of N-Aryl Trifluoroacetimidoyl Chlorides with Alkynes: One-pot Synthesis of Fluorinated Quinolines.
Org. Lett. 2001, 3 (8), 1109-1112.

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Uneyama, K.; Ohkura, H.; Hao, J.; Amii H.
A Trial toward the Synthesis of gamma-Fluorinated-beta-amino-alpha-thioamino Acids. A Finding of Desulfurizative C-C Bond formation in Thio-Wittig Rearrangement of S-(N-Aryltrifluoroacetimidoyl)thioglycolates.
J. Org. Chem. 2001, 66 (3), 1026-1029.

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Abe, H.; Amii, H.; Uneyama, K.
Pd-Catalyzed Asymmetric Hydrogenation of alpha-Fluorinated Iminoesters in Fluorinated Alcohol: A New and Catalytic Enantioselective Synthesis of Fluoro alpha-Amino Acid Derivatives.
Org. Lett. 2001, 3 (3), 313-315.

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2000”N@

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Kobayashi, S.; Yamamoto, Y.; Amii, H.; Uneyama, K.
Preparation and Thermal Behavior of 3,3,4,4-Tetrafluorocyclobutane-1,2-diols; A New Family of Cyclobutane-1,2-diols.
Chem. Lett. 2000 (12), 1366-1367.

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Amii, H.; Kobayashi, T.; Uneyama, K.
A Practical and Highly Efficient Synthesis of a-(Trimethylsilyl)difluoroacetates.
Synthesis-Stuttgart 2000 (14), 2001-2003.

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Mae, M.; Amii, H.; Uneyama, K.
First Synthesis of 3,3-Difluoroserine and Cysteine Derivatives via Mg(0)-promoted Selective C-F Bond Cleavage of Trifluoromethylimines.
Tetrahedron Lett. 2000, 41 (41), 7893-7896.

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Hao, J.; Ohkura, H.; Amii, H.; Uneyama, K.
A Novel Intramolecular Defluorinative Cyclization Approach to the Synthesis of Difluoromethylated Quinazolic Acid Derivatives.
Chem. Commun. 2000 (19), 1883-1884.

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Amii, H.; Kishikawa, Y.; Kageyama, K.; Uneyama, K.
Palladium-Catalyzed tert-Butoxycarbonylation of Trifluoroacetimidoyl Iodides.
J. Org. Chem. 2000, 65 (11), 3404-3408.

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Uneyama, K.; Hiraoka, S.; Amii, H.
Reactions of Benzeneselenenyl Fluoride Generated by XeF
2-(PhSe)2 System with Electron-Deficient Alkenes.
J. Fluorine Chem. 2000, 102 (1-2), 215-218.

1999”N@

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Amii, H.; Kobayashi, T.; Hatamoto, Y.; Uneyama, K.
Mg(0)-Promoted Selective C-F Bond Cleavage of Trifluoromethyl Ketones: A Convenient Method for the Synthesis of 2,2-Difluoro Enol Silanes.
Chem. Commun. 1999 (14), 1323-1324.

1998”N@

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Amii, H.; Kondo, S.; Uneyama, K.
Novel Intramolecular Rearrangement of 3-Bromo-3,3-difluoroalanine Schiff Bases via Radical ipso-Substitution at Aromatic Ring.
Chem. Commun. 1998 (17), 1845-1846.

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Uneyama, K.; Hao, J.; Amii, H.
A Novel Synthesis of b-Trifluoromethyl-Substituted Isoserine via Intramolecular Rearrangement of Imino Ethers.
Tetrahedron Lett. 1998, 39 (23), 4079-4082.

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Murakami, M.; Itahashi, T.; Amii, H.; Takahashi, K.; Ito, Y.
New Domino Sequences Involving Successive Cleavage of Carbon-Carbon and Carbon-Oxygen Bonds: Discrete Product Selection Dictated by Catalyst Ligands.
J. Am. Chem. Soc. 1998, 120 (38), 9949-9950.

1997”N@

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Murakami, M.; Takahashi, K.; Amii, H.; Ito, Y.
Rhodium(I)-Catalyzed Successive Double Cleavage of Carbon-Carbon Bonds of Strained Spiro Cyclobutanones.
J. Am. Chem. Soc. 1997, 119 (39), 9307-9308.

1996”N@

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Murakami, M.; Amii, H.; Shigeto, K.; Ito, Y.
Breaking of the C-C Bond of Cyclobutanones by Rhodium(I) and Its Extention to Catalytic Synthetic Reactions.
J. Am. Chem. Soc. 1996, 118 (35), 8285-8290.

1995”N@

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Murakami, M.; Amii, H.; Itami, K.; Ito, Y.
A Remarkable Effect of Silyl Substitution on Electrocyclization of Vinylallenes.
Angew. Chem. Int. Ed. 1995, 34 (13-14), 1476-1477.

1994”N@

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Murakami, M.; Amii, H.; Ito, Y.
Selective Activation of Carbon-Carbon Bonds next to a Carbonyl Group.
Nature (London) 1994, 370 (6490), 540-541.

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Hada, M.; Tanaka, Y.; Ito, M.; Murakami, M.; Amii, H.; Ito, Y.; Nakatsuji, H.
Theoretical Study on the Reaction Mechanism and Regioselectivity of Silastannation of Acetylenes with a Palladium Catalyst.
J. Am. Chem. Soc. 1994, 116 (19), 8754-8765.

1993”N@

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Murakami, M.; Amii, H.; Takizawa, N.; Ito, Y.
Synthesis of Acylsilanes via Silastannation of Alkynes by a Palladium-Isocyanide Catalyst.
Organometallics 1993, 12 (10), 4223-4227.

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Miyamoto, M.; Amii, H.; Aoi, K.; Saegusa, T.
Double Isomerization Polymerization of Bispseudoureas: A New Cyclopolymerization.
Macromolecules 1993, 26 (6), 1474-1479.

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